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Organic Chemistry

Eyring–Polanyi Linear Form Calculator

Compute Eyring–Polanyi Linear Form using ln(k/T) = −ΔH‡/(R T) + ln(k_B/h) + ΔS‡/R.

ln(k/T) = −ΔH‡/(R T) + ln(k_B/h) + ΔS‡/R

Run this calculator

Leave a nullable field blank to solve for it.

Input variable 'delta_H_dagger' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Input variable 'R' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Input variable 'temperature' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Input variable 'k_B' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Input variable 'h' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Input variable 'delta_S_dagger' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Formula

This calculator uses the equation below. Use it as a quick reference when checking setup before solving.

ln(k/T) = −ΔH‡/(R T) + ln(k_B/h) + ΔS‡/R

Variable glossary

Delta H Dagger (delta_H_dagger)

Input variable 'delta_H_dagger' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

R (R)

Input variable 'R' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Temperature (temperature)

Input variable 'temperature' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

K B (k_B)

Input variable 'k_B' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

H (h)

Input variable 'h' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

Delta S Dagger (delta_S_dagger)

Input variable 'delta_S_dagger' for Eyring–Polanyi Linear Form. Set one variable to null to solve for it.

K (k)

Result variable 'k' for Eyring–Polanyi Linear Form. Set to null (or omit) to compute this value.

Worked example

Try these sample values to validate the setup, then replace inputs with your own conditions.

  • delta_H_dagger: 2
  • R: 3
  • temperature: 298.15
  • k_B: 5
  • h: 6
  • delta_S_dagger: 7

Frequently Asked Questions

What does the Eyring–Polanyi Linear Form calculator solve?

It solves Eyring–Polanyi Linear Form problems in organic chemistry using your provided inputs and computes unknown values when nullable fields are left blank.

Do I need to convert units before using this tool?

Use the unit toggles where available (for example K/C and L/mL). ChemGenius converts values to the calculator's base units automatically before solving.

Can I save this result in my workflow?

Yes. After computing a result, you can continue into ChemGenius workflows like protocol drafting or notes to keep your calculation context attached to downstream work.